The effects of global warming are becoming more serious, and there is a strong demand for technological advances to reduce carbon dioxide emissions. Hydrogen is an ideal clean energy which produces water when burned. To promote the use of hydrogen energy, it is essential to develop safe, energy-saving technologies for hydrogen production and storage. Currently, hydrogen is made from natural gas, so it is not appropriate for decarbonization. Using a lot of energy to separate hydrogen would not make it qualify as clean energy.
Polymer separation membranes have the great advantage of enlarging the separation membrane and increasing the separation coefficient. However, the speed of permeation through the membrane is extremely low, and high pressure must be applied to increase the permeation speed. Therefore, a large amount of energy is required for separation using a polymer separation membrane. The goal is to create a new kind of separation membrane technology that can achieve separation speeds that are 50 times faster than that of conventional separation membranes.
The graphene-wrapped molecular-sieving membrane prepared in this study has a separation factor of 245 and a permeation coefficient of 5.8 x 106 barrers, which is more than 100 times better than that of conventional polymer separation membranes. If the size of the separation membrane is increased in the future, it is very probable that an energy-saving separation process will be established for the separation of important gases such as carbon dioxide and oxygen as well as hydrogen.
As seen in the transmission electron microscope image in Figure 1, graphene is wrapped around the MFI-type zeolite crystal, being hydrophobic. The wrapping uses the principles of colloidal science to keep graphene and zeolite crystal planes close to each other due to reduction of the repulsive interaction. About five layers of graphene enclose zeolite crystals in this figure. Around the red arrow, there is a narrow interface space where only hydrogen can permeate. Graphene is also present on hydrophobic zeolite, so the structure of the zeolite crystal cannot be seen with this. Since a strong attractive force acts between graphene, the zeolite crystals wrapped with graphene are in close contact with each other by a simple compression treatment and does not let any gas through.
In addition, this separation principle is different from the conventional dissolution mechanism with polymers and the separation mechanism with pore size in zeolite separation membranes, and it depends on the separation target by selecting the surface structure of zeolite or another crystal. High-speed separation for any target gas is possible in principle. For this reason, if the industrial manufacturing method of this separation membrane and the separation membrane becomes scalable, the chemical industry, combustion industry, and other industries can enjoy significantly improved energy consumption, leading to a significant reduction in carbon dioxide emissions. Currently, the group is conducting research toward the establishment of basic technology for rapidly producing a large amount of enriched oxygen from air. The development of enriched oxygen manufacturing technologies will revolutionize the steel and chemical industry and even medicine.
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